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The program is running in the background.
The best you can do here is to use multithreading in Python
import threading
command=threading.Thread(target=self.startProgram).start
self.startButton=Button(self,text="Click Here",command=threading.Thread(target=self.startProgram).start,width="50",font=("Times New Roman",15),height="5",bg="red",fg="white")